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Understanding Electrolysis in Water Level Controller Circuits

Many DIY and commercial water level sensing and control circuits are available on the internet. Most of these low-cost designs use metal probes as water sensors. While simple and affordable, they have one major drawback β€” electrolysis.

On the other hand, circuits that use float switches, ultrasonic sensors, or magnetic reed sensors do not suffer from electrolysis. However, they are relatively costly compared to circuits that use direct metal probes.

It’s also important to note that pure water is a poor conductor of electricity. This means that in 100% pure water, a probe-based water level sensing circuit will not work at all.

πŸ” What is Electrolysis?

Electrolysis is the chemical process of breaking down a substance using an electric current. In simple terms, it involves passing electricity through a liquid or molten substance that contains positive (cations) and negative (anions) ions.

  • Two electrodes (metal rods) are dipped into the liquid.
  • These electrodes are connected to a power source such as a battery or DC supply.
  • The electrode connected to the positive terminal becomes the anode and attracts negative ions.
  • The electrode connected to the negative terminal becomes the cathode and attracts positive ions.

This movement of ions causes chemical reactions at the electrodes, which can lead to corrosion, gas formation, or deposits in the water.

⚑ Does Electrolysis Occur in AC and DC?

A common misconception is that electrolysis only occurs in DC circuits. The truth is:

  • DC Circuits β†’ Electrolysis occurs continuously because the current always flows in one direction. This leads to faster electrode wear and more noticeable chemical reactions.
  • AC Circuits β†’ Electrolysis also takes place, but at a much slower rate. This is because the polarity of the electrodes keeps reversing every half cycle, causing the reactions to partially cancel each other out. However, over time, cloudiness and deposits still appear in the water.

πŸ‘‰ This is why AC-based water level controller circuits with probes still experience some level of electrode degradation, though not as fast as DC-based ones.

You can test the electrolysis in AC using the following method:

Parts Required:

  1. A bowl of water with some salt dissolved in it
  2. 2 copper wires used as electrodes.
  3. 9v or 12v stepdown transformer

πŸ› οΈ Steps to Perform the Experiment

1️⃣ Connect the transformer: Attach the primary of the step-down transformer to the 230V AC supply πŸ”Œ.

2️⃣ Attach the electrodes: Connect the electrodes to the secondary of the transformer ⚑.

3️⃣ Prepare the salt water: Fill a bowl with water πŸ’§ and mix in some salt πŸ§‚.

4️⃣ Insert electrodes: Place the electrodes carefully inside the bowl πŸ₯£.

5️⃣ Turn on the power: Switch on the transformer πŸ”‹ and observe.

6️⃣ Notice the reaction: Tiny bubbles 🫧 will start sticking to both electrodes, showing that electrolysis is happening ✨.

πŸ’‘ Why Add Salt?

In pure drinking water 🚰, the reaction is very weak and hard to see. Adding salt πŸ§‚ increases the conductivity, making the electrolysis process much clearer and more visible πŸ‘€.

βœ… Key Takeaways

  • Electrolysis occurs only when the electrode voltage is above the electrolysis threshold (around 1.23 V for water).
  • In conventional DC probe circuits (5 V–12 V), electrolysis is strong, leading to probe corrosion and water contamination.
  • In conventional DC probe circuits (5 V–12 V), electrolysis is strong and causes electrode corrosion.
  • In AC probe circuits, electrolysis is slower but not eliminated, since polarity reversal only reduces the net effect.
  • With a specially designed low-voltage DC sensing circuit (<1.23 V), electrolysis can be completely avoided.



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